Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation

The synthesis of a new C (3v)‐symmetric crushed fullerene C(60)H(24) (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result i...

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Detalles Bibliográficos
Autores principales: Dorel, Ruth, de Mendoza, Paula, Calleja, Pilar, Pascual, Sergio, González‐Cantalapiedra, Esther, Cabello, Noemí, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5053240/
https://www.ncbi.nlm.nih.gov/pubmed/27774038
http://dx.doi.org/10.1002/ejoc.201600311
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author Dorel, Ruth
de Mendoza, Paula
Calleja, Pilar
Pascual, Sergio
González‐Cantalapiedra, Esther
Cabello, Noemí
Echavarren, Antonio M.
author_facet Dorel, Ruth
de Mendoza, Paula
Calleja, Pilar
Pascual, Sergio
González‐Cantalapiedra, Esther
Cabello, Noemí
Echavarren, Antonio M.
author_sort Dorel, Ruth
collection PubMed
description The synthesis of a new C (3v)‐symmetric crushed fullerene C(60)H(24) (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C(60), as detected by LDI‐MS.
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spelling pubmed-50532402016-10-19 Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation Dorel, Ruth de Mendoza, Paula Calleja, Pilar Pascual, Sergio González‐Cantalapiedra, Esther Cabello, Noemí Echavarren, Antonio M. European J Org Chem Full Papers The synthesis of a new C (3v)‐symmetric crushed fullerene C(60)H(24) (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C(60), as detected by LDI‐MS. John Wiley and Sons Inc. 2016-05-02 2016-07 /pmc/articles/PMC5053240/ /pubmed/27774038 http://dx.doi.org/10.1002/ejoc.201600311 Text en © 2016 The Authors. Published by Wiley‐VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Full Papers
Dorel, Ruth
de Mendoza, Paula
Calleja, Pilar
Pascual, Sergio
González‐Cantalapiedra, Esther
Cabello, Noemí
Echavarren, Antonio M.
Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation
title Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation
title_full Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation
title_fullStr Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation
title_full_unstemmed Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation
title_short Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium‐Catalyzed Arylation
title_sort synthesis of a crushed fullerene c60h24 through sixfold palladium‐catalyzed arylation
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5053240/
https://www.ncbi.nlm.nih.gov/pubmed/27774038
http://dx.doi.org/10.1002/ejoc.201600311
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