Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization

The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)‐catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone.

Detalles Bibliográficos
Autores principales: Carreras, Javier, Kirillova, Mariia S., Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5053274/
https://www.ncbi.nlm.nih.gov/pubmed/27119910
http://dx.doi.org/10.1002/anie.201601834
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author Carreras, Javier
Kirillova, Mariia S.
Echavarren, Antonio M.
author_facet Carreras, Javier
Kirillova, Mariia S.
Echavarren, Antonio M.
author_sort Carreras, Javier
collection PubMed
description The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)‐catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone.
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spelling pubmed-50532742016-10-19 Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization Carreras, Javier Kirillova, Mariia S. Echavarren, Antonio M. Angew Chem Int Ed Engl Communications The first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)‐catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone. John Wiley and Sons Inc. 2016-04-27 2016-06-13 /pmc/articles/PMC5053274/ /pubmed/27119910 http://dx.doi.org/10.1002/anie.201601834 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial (http://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Carreras, Javier
Kirillova, Mariia S.
Echavarren, Antonio M.
Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization
title Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization
title_full Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization
title_fullStr Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization
title_full_unstemmed Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization
title_short Synthesis of (−)‐Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)‐Catalyzed Cycloisomerization
title_sort synthesis of (−)‐cannabimovone and structural reassignment of anhydrocannabimovone through gold(i)‐catalyzed cycloisomerization
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5053274/
https://www.ncbi.nlm.nih.gov/pubmed/27119910
http://dx.doi.org/10.1002/anie.201601834
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