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Photochemical Nickel-Catalyzed C–H Arylation: Synthetic Scope and Mechanistic Investigations
[Image: see text] An iridium photocatalyst and visible light facilitate a room temperature, nickel-catalyzed coupling of (hetero)aryl bromides with activated α-heterosubstituted or benzylic C(sp(3))–H bonds. Mechanistic investigations on this unprecedented transformation have uncovered the possibili...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5054938/ https://www.ncbi.nlm.nih.gov/pubmed/27653500 http://dx.doi.org/10.1021/jacs.6b04789 |