Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene

The first hydrogenation step of benzene, which is endergonic in the electronic ground state (S(0)), becomes exergonic in the first triplet state (T(1)). This is in line with Baird's rule, which tells that benzene is antiaromatic and destabilized in its T(1) state and also in its first singlet e...

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Detalles Bibliográficos
Autores principales: Papadakis, Raffaello, Li, Hu, Bergman, Joakim, Lundstedt, Anna, Jorner, Kjell, Ayub, Rabia, Haldar, Soumyajyoti, Jahn, Burkhard O., Denisova, Aleksandra, Zietz, Burkhard, Lindh, Roland, Sanyal, Biplab, Grennberg, Helena, Leifer, Klaus, Ottosson, Henrik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5059713/
https://www.ncbi.nlm.nih.gov/pubmed/27708336
http://dx.doi.org/10.1038/ncomms12962

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