Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors

The electronic and structural properties of two tetrathiafulvalene derivatives bearing aromatic benzene rings are reported. Thin film transistors of these materials show p-type characteristics with comparable mobility values. It is found that the rigidification of the molecule is beneficial for redu...

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Autores principales: Campos, Antonio, Oxtoby, Neil, Galindo, Sergi, Pfattner, Raphael, Veciana, Jaume, Bromley, Stefan T., Rovira, Concepció, Mas-Torrent, Marta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5059789/
https://www.ncbi.nlm.nih.gov/pubmed/27774040
http://dx.doi.org/10.1039/c6ce01200k
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author Campos, Antonio
Oxtoby, Neil
Galindo, Sergi
Pfattner, Raphael
Veciana, Jaume
Bromley, Stefan T.
Rovira, Concepció
Mas-Torrent, Marta
author_facet Campos, Antonio
Oxtoby, Neil
Galindo, Sergi
Pfattner, Raphael
Veciana, Jaume
Bromley, Stefan T.
Rovira, Concepció
Mas-Torrent, Marta
author_sort Campos, Antonio
collection PubMed
description The electronic and structural properties of two tetrathiafulvalene derivatives bearing aromatic benzene rings are reported. Thin film transistors of these materials show p-type characteristics with comparable mobility values. It is found that the rigidification of the molecule is beneficial for reducing the reorganisation energy but also has an unfavorable impact on the electronic structure dimensionality.
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spelling pubmed-50597892016-10-19 Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors Campos, Antonio Oxtoby, Neil Galindo, Sergi Pfattner, Raphael Veciana, Jaume Bromley, Stefan T. Rovira, Concepció Mas-Torrent, Marta CrystEngComm Chemistry The electronic and structural properties of two tetrathiafulvalene derivatives bearing aromatic benzene rings are reported. Thin film transistors of these materials show p-type characteristics with comparable mobility values. It is found that the rigidification of the molecule is beneficial for reducing the reorganisation energy but also has an unfavorable impact on the electronic structure dimensionality. Royal Society of Chemistry 2016-09-07 2016-07-12 /pmc/articles/PMC5059789/ /pubmed/27774040 http://dx.doi.org/10.1039/c6ce01200k Text en This journal is © The Royal Society of Chemistry 2016 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Campos, Antonio
Oxtoby, Neil
Galindo, Sergi
Pfattner, Raphael
Veciana, Jaume
Bromley, Stefan T.
Rovira, Concepció
Mas-Torrent, Marta
Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors
title Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors
title_full Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors
title_fullStr Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors
title_full_unstemmed Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors
title_short Structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors
title_sort structural and electronic characterisation of π-extended tetrathiafulvalene derivatives as active components in field-effect transistors
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5059789/
https://www.ncbi.nlm.nih.gov/pubmed/27774040
http://dx.doi.org/10.1039/c6ce01200k
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