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Mechanistic Investigation into Olefin Epoxidation with H(2)O(2) Catalyzed by Aqua‐Coordinated Sandwich‐Type Polyoxometalates: Role of the Noble Metal and Active Oxygen Position
Aqua‐coordinated sandwich‐type polyoxometalates (POMs), {[WZnTM(2)(H(2)O)(2)](ZnW(9)O(34))(2)}(n−) (TM=Rh(III), Pd(II), and Pt(II)), catalyze olefin epoxidation with hydrogen peroxide and have been well established, and they present an advance toward the utilization of olefins. To elucidate the epox...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5062013/ https://www.ncbi.nlm.nih.gov/pubmed/27777840 http://dx.doi.org/10.1002/open.201600064 |