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Iron‐ and Cobalt‐Catalyzed Synthesis of Carbene Phosphinidenes
In the presence of stoichiometric or catalytic amounts of [M{N(SiMe(3))(2)}(2)] (M=Fe, Co), N‐heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)⋅PAr. The formation of (IMe(4))⋅PMes (Mes=mesityl) is also catalyzed by the phosphinide...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5064616/ https://www.ncbi.nlm.nih.gov/pubmed/26643712 http://dx.doi.org/10.1002/anie.201508303 |