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Identifying and rationalizing the morphological, structural, and optical properties of [Image: see text]-Ag(2)MoO(4) microcrystals, and the formation process of Ag nanoparticles on their surfaces: combining experimental data and first-principles calculations

We present a combined theoretical and experimental study on the morphological, structural, and optical properties of β-Ag(2)MoO(4) microcrystals. β-Ag(2)MoO(4) samples were prepared by a co-precipitation method. The nucleation and formation of Ag nanoparticles on β-Ag(2)MoO(4) during electron beam i...

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Detalles Bibliográficos
Autores principales: Fabbro, Maria T, Saliby, Carla, Rios, Larissa R, La Porta, Felipe A, Gracia, Lourdes, Li, Máximo S, Andrés, Juan, Santos, Luís P S, Longo, Elson
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5069988/
https://www.ncbi.nlm.nih.gov/pubmed/27877844
http://dx.doi.org/10.1088/1468-6996/16/6/065002
Descripción
Sumario:We present a combined theoretical and experimental study on the morphological, structural, and optical properties of β-Ag(2)MoO(4) microcrystals. β-Ag(2)MoO(4) samples were prepared by a co-precipitation method. The nucleation and formation of Ag nanoparticles on β-Ag(2)MoO(4) during electron beam irradiation were also analyzed as a function of electron beam dose. These events were directly monitored in real-time using in situ field emission scanning electron microscopy (FE-SEM). The thermodynamic equilibrium shape of the β-Ag(2)MoO(4) crystals was built with low-index surfaces (001), (011), and (111) through a Wulff construction. This shape suggests that the (011) face is the dominating surface in the ideal morphology. A significant increase in the values of the surface energy for the (011) face versus those of the other surfaces was observed, which allowed us to find agreement between the experimental and theoretical morphologies. Our investigation of the different morphologies and structures of the β-Ag(2)MoO(4) crystals provided insight into how the crystal morphology can be controlled so that the surface chemistry of β-Ag(2)MoO(4) can be tuned for specific applications. The presence of structural disorder in the tetrahedral [MoO(4)] and octahedral [AgO(6)] clusters, the building blocks of β-Ag(2)MoO(4), was used to explain the experimentally measured optical properties.