The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation

In a multi-component homogeneous system, the relationship between partial molar and molar quantity (RPMQ) is proved to be an equivalent relation of the Gibbs-Duhem equation. The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation are inferred from the RPMQ. Base...

Descripción completa

Detalles Bibliográficos
Autor principal: Tao, Dong-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5071892/
https://www.ncbi.nlm.nih.gov/pubmed/27762329
http://dx.doi.org/10.1038/srep35792
_version_ 1782461347350446080
author Tao, Dong-Ping
author_facet Tao, Dong-Ping
author_sort Tao, Dong-Ping
collection PubMed
description In a multi-component homogeneous system, the relationship between partial molar and molar quantity (RPMQ) is proved to be an equivalent relation of the Gibbs-Duhem equation. The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation are inferred from the RPMQ. Based on the inference, an asymmetric regular solution model is suggested to deal with those systems that exhibit strong negative deviation, strong positive deviation, and both strong positive and negative deviation from ideality.
format Online
Article
Text
id pubmed-5071892
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher Nature Publishing Group
record_format MEDLINE/PubMed
spelling pubmed-50718922016-10-26 The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation Tao, Dong-Ping Sci Rep Article In a multi-component homogeneous system, the relationship between partial molar and molar quantity (RPMQ) is proved to be an equivalent relation of the Gibbs-Duhem equation. The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation are inferred from the RPMQ. Based on the inference, an asymmetric regular solution model is suggested to deal with those systems that exhibit strong negative deviation, strong positive deviation, and both strong positive and negative deviation from ideality. Nature Publishing Group 2016-10-20 /pmc/articles/PMC5071892/ /pubmed/27762329 http://dx.doi.org/10.1038/srep35792 Text en Copyright © 2016, The Author(s) http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Tao, Dong-Ping
The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation
title The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation
title_full The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation
title_fullStr The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation
title_full_unstemmed The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation
title_short The universal characteristics of a thermodynamic model to conform to the Gibbs-Duhem equation
title_sort universal characteristics of a thermodynamic model to conform to the gibbs-duhem equation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5071892/
https://www.ncbi.nlm.nih.gov/pubmed/27762329
http://dx.doi.org/10.1038/srep35792
work_keys_str_mv AT taodongping theuniversalcharacteristicsofathermodynamicmodeltoconformtothegibbsduhemequation
AT taodongping universalcharacteristicsofathermodynamicmodeltoconformtothegibbsduhemequation

Ejemplares similares