Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement

We hereby present the new class of ionic liquid systems in which lithium salt is introduced into the solution as a lithium cation−glyme solvate. This modification leads to the reorganisation of solution structure, which entails release of free mobile lithium cation solvate and hence leads to the sig...

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Detalles Bibliográficos
Autores principales: Karpierz, E., Niedzicki, L., Trzeciak, T., Zawadzki, M., Dranka, M., Zachara, J., Żukowska, G. Z., Bitner-Michalska, A., Wieczorek, W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5073297/
https://www.ncbi.nlm.nih.gov/pubmed/27767069
http://dx.doi.org/10.1038/srep35587
Descripción
Sumario:We hereby present the new class of ionic liquid systems in which lithium salt is introduced into the solution as a lithium cation−glyme solvate. This modification leads to the reorganisation of solution structure, which entails release of free mobile lithium cation solvate and hence leads to the significant enhancement of ionic conductivity and lithium cation transference numbers. This new approach in composing electrolytes also enables even three-fold increase of salt concentration in ionic liquids.

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