Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement

We hereby present the new class of ionic liquid systems in which lithium salt is introduced into the solution as a lithium cation−glyme solvate. This modification leads to the reorganisation of solution structure, which entails release of free mobile lithium cation solvate and hence leads to the sig...

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Autores principales: Karpierz, E., Niedzicki, L., Trzeciak, T., Zawadzki, M., Dranka, M., Zachara, J., Żukowska, G. Z., Bitner-Michalska, A., Wieczorek, W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5073297/
https://www.ncbi.nlm.nih.gov/pubmed/27767069
http://dx.doi.org/10.1038/srep35587
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author Karpierz, E.
Niedzicki, L.
Trzeciak, T.
Zawadzki, M.
Dranka, M.
Zachara, J.
Żukowska, G. Z.
Bitner-Michalska, A.
Wieczorek, W.
author_facet Karpierz, E.
Niedzicki, L.
Trzeciak, T.
Zawadzki, M.
Dranka, M.
Zachara, J.
Żukowska, G. Z.
Bitner-Michalska, A.
Wieczorek, W.
author_sort Karpierz, E.
collection PubMed
description We hereby present the new class of ionic liquid systems in which lithium salt is introduced into the solution as a lithium cation−glyme solvate. This modification leads to the reorganisation of solution structure, which entails release of free mobile lithium cation solvate and hence leads to the significant enhancement of ionic conductivity and lithium cation transference numbers. This new approach in composing electrolytes also enables even three-fold increase of salt concentration in ionic liquids.
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spelling pubmed-50732972016-10-26 Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement Karpierz, E. Niedzicki, L. Trzeciak, T. Zawadzki, M. Dranka, M. Zachara, J. Żukowska, G. Z. Bitner-Michalska, A. Wieczorek, W. Sci Rep Article We hereby present the new class of ionic liquid systems in which lithium salt is introduced into the solution as a lithium cation−glyme solvate. This modification leads to the reorganisation of solution structure, which entails release of free mobile lithium cation solvate and hence leads to the significant enhancement of ionic conductivity and lithium cation transference numbers. This new approach in composing electrolytes also enables even three-fold increase of salt concentration in ionic liquids. Nature Publishing Group 2016-10-21 /pmc/articles/PMC5073297/ /pubmed/27767069 http://dx.doi.org/10.1038/srep35587 Text en Copyright © 2016, The Author(s) http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Karpierz, E.
Niedzicki, L.
Trzeciak, T.
Zawadzki, M.
Dranka, M.
Zachara, J.
Żukowska, G. Z.
Bitner-Michalska, A.
Wieczorek, W.
Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement
title Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement
title_full Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement
title_fullStr Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement
title_full_unstemmed Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement
title_short Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement
title_sort ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5073297/
https://www.ncbi.nlm.nih.gov/pubmed/27767069
http://dx.doi.org/10.1038/srep35587
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