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The 2‐Arsaethynolate Anion: Synthesis and Reactivity Towards Heteroallenes
The synthesis and isolation of the 2‐arsaethynolate anion, AsCO(−), and its subsequent reactivity towards heteroallenes is reported. Reactions with ketenes and carbodiimides afford four‐membered anionic heterocycles in formal [2+2] cycloaddition reactions. By contrast, reaction with an isocyanate yi...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5074235/ https://www.ncbi.nlm.nih.gov/pubmed/27093942 http://dx.doi.org/10.1002/anie.201602310 |