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The 2‐Arsaethynolate Anion: Synthesis and Reactivity Towards Heteroallenes

The synthesis and isolation of the 2‐arsaethynolate anion, AsCO(−), and its subsequent reactivity towards heteroallenes is reported. Reactions with ketenes and carbodiimides afford four‐membered anionic heterocycles in formal [2+2] cycloaddition reactions. By contrast, reaction with an isocyanate yi...

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Detalles Bibliográficos
Autores principales:	Hinz, Alexander, Goicoechea, Jose M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5074235/ https://www.ncbi.nlm.nih.gov/pubmed/27093942 http://dx.doi.org/10.1002/anie.201602310

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