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Palladium-catalyzed ring-opening reactions of cyclopropanated 7-oxabenzonorbornadiene with alcohols

Palladium-catalyzed ring-opening reactions of cyclopropanated 7-oxabenzonorbornadiene derivatives using alcohol nucleophiles were investigated. The optimal conditions were found to be 10 mol % PdCl(2)(CH(3)CN)(2) in methanol, offering yields up to 92%. The reaction was successful using primary, seco...

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Detalles Bibliográficos
Autores principales: Tait, Katrina, Alrifai, Oday, Boutin, Rebecca, Haner, Jamie, Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5082584/
https://www.ncbi.nlm.nih.gov/pubmed/27829926
http://dx.doi.org/10.3762/bjoc.12.209