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Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correct...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5082723/ https://www.ncbi.nlm.nih.gov/pubmed/27829894 http://dx.doi.org/10.3762/bjoc.12.177 |
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author | Kotha, Sambasivarao Gunta, Rama |
author_facet | Kotha, Sambasivarao Gunta, Rama |
author_sort | Kotha, Sambasivarao |
collection | PubMed |
description | Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules. |
format | Online Article Text |
id | pubmed-5082723 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2016 |
publisher | Beilstein-Institut |
record_format | MEDLINE/PubMed |
spelling | pubmed-50827232016-11-09 Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis Kotha, Sambasivarao Gunta, Rama Beilstein J Org Chem Full Research Paper Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules. Beilstein-Institut 2016-08-22 /pmc/articles/PMC5082723/ /pubmed/27829894 http://dx.doi.org/10.3762/bjoc.12.177 Text en Copyright © 2016, Kotha and Gunta https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
spellingShingle | Full Research Paper Kotha, Sambasivarao Gunta, Rama Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis |
title | Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis |
title_full | Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis |
title_fullStr | Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis |
title_full_unstemmed | Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis |
title_short | Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis |
title_sort | bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis |
topic | Full Research Paper |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5082723/ https://www.ncbi.nlm.nih.gov/pubmed/27829894 http://dx.doi.org/10.3762/bjoc.12.177 |
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