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Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correct...

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Autores principales: Kotha, Sambasivarao, Gunta, Rama
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5082723/
https://www.ncbi.nlm.nih.gov/pubmed/27829894
http://dx.doi.org/10.3762/bjoc.12.177
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author Kotha, Sambasivarao
Gunta, Rama
author_facet Kotha, Sambasivarao
Gunta, Rama
author_sort Kotha, Sambasivarao
collection PubMed
description Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.
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spelling pubmed-50827232016-11-09 Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis Kotha, Sambasivarao Gunta, Rama Beilstein J Org Chem Full Research Paper Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules. Beilstein-Institut 2016-08-22 /pmc/articles/PMC5082723/ /pubmed/27829894 http://dx.doi.org/10.3762/bjoc.12.177 Text en Copyright © 2016, Kotha and Gunta https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kotha, Sambasivarao
Gunta, Rama
Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_full Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_fullStr Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_full_unstemmed Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_short Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
title_sort bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5082723/
https://www.ncbi.nlm.nih.gov/pubmed/27829894
http://dx.doi.org/10.3762/bjoc.12.177
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