Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal Geometry in Determining the Reaction Outcome

[Image: see text] 2-Alkenylphenols react with allenes, upon treatment with catalytic amounts of Pd(II) and Cu(II), to give benzoxepine products in high yields and with very good regio- and diastereoselectivities. This contrasts with the results obtained with Rh catalysts, which provided chromene-lik...

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Detalles Bibliográficos
Autores principales: Casanova, Noelia, Del Rio, Karina P., García-Fandiño, Rebeca, Mascareñas, José L., Gulías, Moisés
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2016
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5084065/
https://www.ncbi.nlm.nih.gov/pubmed/27807509
http://dx.doi.org/10.1021/acscatal.6b00739

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5084065/
https://www.ncbi.nlm.nih.gov/pubmed/27807509
http://dx.doi.org/10.1021/acscatal.6b00739

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