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Highly Enantioselective Iridium‐Catalyzed Hydrogenation of Cyclic Enamides

The MaxPHOX–Ir catalyst system provided the highest selectivity ever reported for the reduction of cyclic enamides derived from α‐ and β‐tetralones. This result indicates that iridium catalysts are also proficient in reducing alkenes bearing metal‐coordinating groups. In the present system, selectiv...

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Detalles Bibliográficos
Autores principales: Salomó, Ernest, Orgué, Sílvia, Riera, Antoni, Verdaguer, Xavier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5084810/
https://www.ncbi.nlm.nih.gov/pubmed/27186653
http://dx.doi.org/10.1002/anie.201602219