Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts

The radical carbohydroxylation of styrenes with aryldiazonium salts has been achieved under mild thermal conditions. A broad range of aryldiazonium salts was tolerated, and the reaction principle based on a radical–polar crossover mechanism could be extended to carboetherification as well as to a tw...

Descripción completa

Detalles Bibliográficos
Autores principales: Kindt, Stephanie, Wicht, Karina, Heinrich, Markus R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5089591/
https://www.ncbi.nlm.nih.gov/pubmed/27273583
http://dx.doi.org/10.1002/anie.201601656
_version_ 1782464261439619072
author Kindt, Stephanie
Wicht, Karina
Heinrich, Markus R.
author_facet Kindt, Stephanie
Wicht, Karina
Heinrich, Markus R.
author_sort Kindt, Stephanie
collection PubMed
description The radical carbohydroxylation of styrenes with aryldiazonium salts has been achieved under mild thermal conditions. A broad range of aryldiazonium salts was tolerated, and the reaction principle based on a radical–polar crossover mechanism could be extended to carboetherification as well as to a two‐step, metal‐free variant of the Meerwein arylation leading to stilbenes.
format Online
Article
Text
id pubmed-5089591
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-50895912016-11-09 Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts Kindt, Stephanie Wicht, Karina Heinrich, Markus R. Angew Chem Int Ed Engl Communications The radical carbohydroxylation of styrenes with aryldiazonium salts has been achieved under mild thermal conditions. A broad range of aryldiazonium salts was tolerated, and the reaction principle based on a radical–polar crossover mechanism could be extended to carboetherification as well as to a two‐step, metal‐free variant of the Meerwein arylation leading to stilbenes. John Wiley and Sons Inc. 2016-06-08 2016-07-18 /pmc/articles/PMC5089591/ /pubmed/27273583 http://dx.doi.org/10.1002/anie.201601656 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Kindt, Stephanie
Wicht, Karina
Heinrich, Markus R.
Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts
title Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts
title_full Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts
title_fullStr Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts
title_full_unstemmed Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts
title_short Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts
title_sort thermally induced carbohydroxylation of styrenes with aryldiazonium salts
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5089591/
https://www.ncbi.nlm.nih.gov/pubmed/27273583
http://dx.doi.org/10.1002/anie.201601656
work_keys_str_mv AT kindtstephanie thermallyinducedcarbohydroxylationofstyreneswitharyldiazoniumsalts
AT wichtkarina thermallyinducedcarbohydroxylationofstyreneswitharyldiazoniumsalts
AT heinrichmarkusr thermallyinducedcarbohydroxylationofstyreneswitharyldiazoniumsalts

Ejemplares similares