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A New Ir‐NHC Catalyst for Signal Amplification by Reversible Exchange in D(2)O

NMR signal amplification by reversible exchange (SABRE) has been observed for pyridine, methyl nicotinate, N‐methylnicotinamide, and nicotinamide in D(2)O with the new catalyst [Ir(Cl)(IDEG)(COD)] (IDEG=1,3‐bis(3,4,5‐tris(diethyleneglycol)benzyl)imidazole‐2‐ylidene). During the activation and hyperp...

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Detalles Bibliográficos
Autores principales: Spannring, Peter, Reile, Indrek, Emondts, Meike, Schleker, Philipp P. M., Hermkens, Niels K. J., van der Zwaluw, Nick G. J., van Weerdenburg, Bram J. A., Tinnemans, Paul, Tessari, Marco, Blümich, Bernhard, Rutjes, Floris P. J. T., Feiters, Martin C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5089654/
https://www.ncbi.nlm.nih.gov/pubmed/27258850
http://dx.doi.org/10.1002/chem.201601211

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