Controlled processing of (Gd,Ln)(2)O(3):Eu (Ln = Y, Lu) red phosphor particles and compositional effects on photoluminescence

Synthesis of (Gd(0.95−x)Ln(x)Eu(0.05))(2)O(3) (Ln = Y and Lu, x = 0–0.95) powders via ammonium hydrogen carbonate (AHC) precipitation has been systematically studied. The best synthesis parameters are found to be an AHC/total cation molar ratio of 4.5 and an ageing time of 3 h. The effects of Y(3+) and Lu(3+) substitution for Gd(3+), on the nucleation kinetics of the precursors and structural features and optical properties of the oxides, have been investigated. The results show that (i) different nucleation kinetics exist in the Gd–Y–Eu and Gd–Lu–Eu ternary systems, which lead to various morphologies and particle sizes of the precipitated precursors. The (Gd,Y)(2)O(3):Eu precursors display spherical particle morphologies and the particle sizes increase along with more Y(3+) addition. The (Gd,Lu)(2)O(3):Eu precursors, on the other hand, are hollow spheres and the particle sizes increase with increasing Lu(3+) incorporation, (ii) the resultant oxide powders are ultrafine, narrow in size distribution, well dispersed and rounded in particle shape, (iii) lattice parameters of the two kinds of oxide solid solutions linearly decrease at a higher Y(3+) or Lu(3+) content. Their theoretical densities linearly decrease with increasing Y(3+) incorporation, but increase along with more Lu(3+) addition and (iv) the two kinds of phosphors exhibit typical red emissions at ∼613 nm and their charge-transfer bands blue shift at a higher Y(3+) or Lu(3+) content. Photoluminescence/photoluminescence excitation intensities and external quantum efficiency are found to decrease with increasing value of x, and the fluorescence lifetime mainly depends on the specific surface areas of the powders.