Activation of Al–Cu–Fe quasicrystalline surface: fabrication of a fine nanocomposite layer with high catalytic performance

A fine layered nanocomposite with a total thickness of about 200 nm was formed on the surface of an Al(63)Cu(25)Fe(12) quasicrystal (QC). The nanocomposite was found to exhibit high catalytic performance for steam reforming of methanol. The nanocomposite was formed by a self-assembly process, by leaching the Al–Cu–Fe QC using a 5 wt% Na(2)CO(3) aqueous solution followed by calcination in air at 873 K. The quasiperiodic nature of theQC played an important role in the formation of such a structure. Its high catalytic activity originated from the presence of highly dispersed copper and iron species, which also suppressed the sintering of nanoparticles.