Classical/Non‐classical Polyoxometalate Hybrids

Two polyanions [Se(I V) (2)Pd(II) (4)W(VI) (14)O(56)H](11−) and [Se(I V) (4)Pd(II) (4)W(VI) (28)O(108)H(12)](12−) are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non‐classical (late transition‐metal based) polyoxometalate units are joined. Requiring no supporting...

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Detalles Bibliográficos
Autores principales: Izarova, Natalya V., Santiago‐Schübel, Beatrix, Willbold, Sabine, Heß, Volkmar, Kögerler, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095796/
https://www.ncbi.nlm.nih.gov/pubmed/27617918
http://dx.doi.org/10.1002/chem.201604238
Descripción
Sumario:Two polyanions [Se(I V) (2)Pd(II) (4)W(VI) (14)O(56)H](11−) and [Se(I V) (4)Pd(II) (4)W(VI) (28)O(108)H(12)](12−) are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non‐classical (late transition‐metal based) polyoxometalate units are joined. Requiring no supporting groups, this co‐condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM‐Pd(II) coordination complexes and the young subclass of polyoxopalladates. Solid‐state, solution, and gas‐phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.

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