Classical/Non‐classical Polyoxometalate Hybrids

Two polyanions [Se(I V) (2)Pd(II) (4)W(VI) (14)O(56)H](11−) and [Se(I V) (4)Pd(II) (4)W(VI) (28)O(108)H(12)](12−) are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non‐classical (late transition‐metal based) polyoxometalate units are joined. Requiring no supporting...

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Autores principales: Izarova, Natalya V., Santiago‐Schübel, Beatrix, Willbold, Sabine, Heß, Volkmar, Kögerler, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095796/
https://www.ncbi.nlm.nih.gov/pubmed/27617918
http://dx.doi.org/10.1002/chem.201604238
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author Izarova, Natalya V.
Santiago‐Schübel, Beatrix
Willbold, Sabine
Heß, Volkmar
Kögerler, Paul
author_facet Izarova, Natalya V.
Santiago‐Schübel, Beatrix
Willbold, Sabine
Heß, Volkmar
Kögerler, Paul
author_sort Izarova, Natalya V.
collection PubMed
description Two polyanions [Se(I V) (2)Pd(II) (4)W(VI) (14)O(56)H](11−) and [Se(I V) (4)Pd(II) (4)W(VI) (28)O(108)H(12)](12−) are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non‐classical (late transition‐metal based) polyoxometalate units are joined. Requiring no supporting groups, this co‐condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM‐Pd(II) coordination complexes and the young subclass of polyoxopalladates. Solid‐state, solution, and gas‐phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies.
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spelling pubmed-50957962016-11-09 Classical/Non‐classical Polyoxometalate Hybrids Izarova, Natalya V. Santiago‐Schübel, Beatrix Willbold, Sabine Heß, Volkmar Kögerler, Paul Chemistry Communications Two polyanions [Se(I V) (2)Pd(II) (4)W(VI) (14)O(56)H](11−) and [Se(I V) (4)Pd(II) (4)W(VI) (28)O(108)H(12)](12−) are the first hybrid polyoxometalates in which classical (Group 5/6 metal based) and non‐classical (late transition‐metal based) polyoxometalate units are joined. Requiring no supporting groups, this co‐condensation of polyoxotungstate and isopolyoxopalladate constituents also provides a logical link between POM‐Pd(II) coordination complexes and the young subclass of polyoxopalladates. Solid‐state, solution, and gas‐phase studies suggest interesting specific reactivities for these hybrids and point to several potential derivatives and functionalization strategies. John Wiley and Sons Inc. 2016-10-05 2016-11-02 /pmc/articles/PMC5095796/ /pubmed/27617918 http://dx.doi.org/10.1002/chem.201604238 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Izarova, Natalya V.
Santiago‐Schübel, Beatrix
Willbold, Sabine
Heß, Volkmar
Kögerler, Paul
Classical/Non‐classical Polyoxometalate Hybrids
title Classical/Non‐classical Polyoxometalate Hybrids
title_full Classical/Non‐classical Polyoxometalate Hybrids
title_fullStr Classical/Non‐classical Polyoxometalate Hybrids
title_full_unstemmed Classical/Non‐classical Polyoxometalate Hybrids
title_short Classical/Non‐classical Polyoxometalate Hybrids
title_sort classical/non‐classical polyoxometalate hybrids
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095796/
https://www.ncbi.nlm.nih.gov/pubmed/27617918
http://dx.doi.org/10.1002/chem.201604238
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