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Dimethylammonium 2,4,5-tricarboxybenzoate: an example of the decarbonylation of N,N-dimethylformamide in the presence of a metal and a benzenepolycarboxylic acid. Is zirconium(IV) the Tsotsi?
The title salt, C(2)H(8)N(+)·C(10)H(5)O(8) (−), was the unexpected product of an attempt to prepare a Zr(IV) metal–organic framework with benzene-1,2,4,5-tetracarboxylic acid (1,2,4,5-H(3)B4C). In the reaction, the DMF solvent has been decarbonylated, forming the dimethylammonium cation, wit...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095824/ https://www.ncbi.nlm.nih.gov/pubmed/27840699 http://dx.doi.org/10.1107/S2056989016014948 |