Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide

In the title compound, C(14)H(15)NO(4)S, the di­hydro­thia­zine ring adopts a distorted sofa conformation with the S atom displaced from the mean plane through the N and C ring atoms by 0.767 (1) Å. The allyl substituent (C—C=C) is inclined to this mean plane by 78.5 (7)° and the acetate group [C(=O...

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Autores principales: Azotla-Cruz, Liliana, Shishkina, Svitlana, Ukrainets, Igor, Lijanova, Irina, Likhanova, Natalya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095836/
https://www.ncbi.nlm.nih.gov/pubmed/27840711
http://dx.doi.org/10.1107/S2056989016015978
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author Azotla-Cruz, Liliana
Shishkina, Svitlana
Ukrainets, Igor
Lijanova, Irina
Likhanova, Natalya
author_facet Azotla-Cruz, Liliana
Shishkina, Svitlana
Ukrainets, Igor
Lijanova, Irina
Likhanova, Natalya
author_sort Azotla-Cruz, Liliana
collection PubMed
description In the title compound, C(14)H(15)NO(4)S, the di­hydro­thia­zine ring adopts a distorted sofa conformation with the S atom displaced from the mean plane through the N and C ring atoms by 0.767 (1) Å. The allyl substituent (C—C=C) is inclined to this mean plane by 78.5 (7)° and the acetate group [C(=O)—O—C] by 66.5 (3)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions forming chains propagating along the a-axis direction.
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spelling pubmed-50958362016-11-11 Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide Azotla-Cruz, Liliana Shishkina, Svitlana Ukrainets, Igor Lijanova, Irina Likhanova, Natalya Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(14)H(15)NO(4)S, the di­hydro­thia­zine ring adopts a distorted sofa conformation with the S atom displaced from the mean plane through the N and C ring atoms by 0.767 (1) Å. The allyl substituent (C—C=C) is inclined to this mean plane by 78.5 (7)° and the acetate group [C(=O)—O—C] by 66.5 (3)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions forming chains propagating along the a-axis direction. International Union of Crystallography 2016-10-14 /pmc/articles/PMC5095836/ /pubmed/27840711 http://dx.doi.org/10.1107/S2056989016015978 Text en © Azotla-Cruz et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Azotla-Cruz, Liliana
Shishkina, Svitlana
Ukrainets, Igor
Lijanova, Irina
Likhanova, Natalya
Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide
title Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide
title_full Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide
title_fullStr Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide
title_full_unstemmed Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide
title_short Crystal structure of methyl 1-allyl-4-methyl-1H-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide
title_sort crystal structure of methyl 1-allyl-4-methyl-1h-benzo[c][1,2]thia­zine-3-carboxyl­ate 2,2-dioxide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095836/
https://www.ncbi.nlm.nih.gov/pubmed/27840711
http://dx.doi.org/10.1107/S2056989016015978
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