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Crystal structure of 1-phenylimido-1-{6-[1-(phenylimino)ethyl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II)
The title iron complex, [Fe(C(21)H(19)N(3))(2)], consists of an Fe(II) atom chelated by two tridentate bis(imino)pyridine radical anions in a slightly distorted octahedral coordination environment. In the solid state, there are two independent half-molecules in the asymmetric unit, and the compl...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095841/ https://www.ncbi.nlm.nih.gov/pubmed/27840716 http://dx.doi.org/10.1107/S2056989016015528 |
Sumario: | The title iron complex, [Fe(C(21)H(19)N(3))(2)], consists of an Fe(II) atom chelated by two tridentate bis(imino)pyridine radical anions in a slightly distorted octahedral coordination environment. In the solid state, there are two independent half-molecules in the asymmetric unit, and the complete molecular structure is formed by applying twofold rotation symmetry with the twofold rotation axis passing through an Fe atom. In the crystal, the Fe-containing complexes are not involved in any particular direct intermolecular interactions, with the shortest C—H(Ar) contacts between neighboring phenyl groups being ca 3.2 Å. |
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