Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II)

The title iron complex, [Fe(C(21)H(19)N(3))(2)], consists of an Fe(II) atom chelated by two tridentate bis­(imino)­pyridine radical anions in a slightly distorted octa­hedral coordination environment. In the solid state, there are two independent half-mol­ecules in the asymmetric unit, and the compl...

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Detalles Bibliográficos
Autores principales: Lau, Ka-Cheong, Filatov, Alexander S., Jordan, Richard F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095841/
https://www.ncbi.nlm.nih.gov/pubmed/27840716
http://dx.doi.org/10.1107/S2056989016015528
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author Lau, Ka-Cheong
Filatov, Alexander S.
Jordan, Richard F.
author_facet Lau, Ka-Cheong
Filatov, Alexander S.
Jordan, Richard F.
author_sort Lau, Ka-Cheong
collection PubMed
description The title iron complex, [Fe(C(21)H(19)N(3))(2)], consists of an Fe(II) atom chelated by two tridentate bis­(imino)­pyridine radical anions in a slightly distorted octa­hedral coordination environment. In the solid state, there are two independent half-mol­ecules in the asymmetric unit, and the complete mol­ecular structure is formed by applying twofold rotation symmetry with the twofold rotation axis passing through an Fe atom. In the crystal, the Fe-containing complexes are not involved in any particular direct inter­molecular inter­actions, with the shortest C—H(Ar) contacts between neighboring phenyl groups being ca 3.2 Å.
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spelling pubmed-50958412016-11-11 Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II) Lau, Ka-Cheong Filatov, Alexander S. Jordan, Richard F. Acta Crystallogr E Crystallogr Commun Research Communications The title iron complex, [Fe(C(21)H(19)N(3))(2)], consists of an Fe(II) atom chelated by two tridentate bis­(imino)­pyridine radical anions in a slightly distorted octa­hedral coordination environment. In the solid state, there are two independent half-mol­ecules in the asymmetric unit, and the complete mol­ecular structure is formed by applying twofold rotation symmetry with the twofold rotation axis passing through an Fe atom. In the crystal, the Fe-containing complexes are not involved in any particular direct inter­molecular inter­actions, with the shortest C—H(Ar) contacts between neighboring phenyl groups being ca 3.2 Å. International Union of Crystallography 2016-10-18 /pmc/articles/PMC5095841/ /pubmed/27840716 http://dx.doi.org/10.1107/S2056989016015528 Text en © Lau et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Lau, Ka-Cheong
Filatov, Alexander S.
Jordan, Richard F.
Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II)
title Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II)
title_full Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II)
title_fullStr Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II)
title_full_unstemmed Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II)
title_short Crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) N,N′,N′′)iron(II)
title_sort crystal structure of 1-phenyl­imido-1-{6-[1-(phenyl­imino)­eth­yl]pyridin-2-yl}ethan-1-yl-κ(3) n,n′,n′′)iron(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095841/
https://www.ncbi.nlm.nih.gov/pubmed/27840716
http://dx.doi.org/10.1107/S2056989016015528
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