Crystal structure of N,N,N-tri­ethyl­hydroxyl­ammonium chloride

In the title mol­ecular salt, C(6)H(16)NO(+)·Cl(−), two of the C—C—N—O groups in the cation adopt a gauche conformation [torsion angles = 62.86 (11) and −54.95 (13)°] and one an anti conformation [−177.82 (10)°. The cation and anion are linked by an O—H⋯Cl hydrogen bond. The extended structure displ...

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Autores principales: Averkiev, Boris B., Valencia, Bianca C., Getmanenko, Yulia A., Timofeeva, Tatiana V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095844/
https://www.ncbi.nlm.nih.gov/pubmed/27840719
http://dx.doi.org/10.1107/S2056989016016169
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author Averkiev, Boris B.
Valencia, Bianca C.
Getmanenko, Yulia A.
Timofeeva, Tatiana V.
author_facet Averkiev, Boris B.
Valencia, Bianca C.
Getmanenko, Yulia A.
Timofeeva, Tatiana V.
author_sort Averkiev, Boris B.
collection PubMed
description In the title mol­ecular salt, C(6)H(16)NO(+)·Cl(−), two of the C—C—N—O groups in the cation adopt a gauche conformation [torsion angles = 62.86 (11) and −54.95 (13)°] and one an anti conformation [−177.82 (10)°. The cation and anion are linked by an O—H⋯Cl hydrogen bond. The extended structure displays C—H⋯Cl and C—H⋯O hydrogen bonds, resulting in layers lying parallel to the (100) plane: further C—H⋯Cl contacts connect the sheets into a three-dimensional network.
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spelling pubmed-50958442016-11-11 Crystal structure of N,N,N-tri­ethyl­hydroxyl­ammonium chloride Averkiev, Boris B. Valencia, Bianca C. Getmanenko, Yulia A. Timofeeva, Tatiana V. Acta Crystallogr E Crystallogr Commun Research Communications In the title mol­ecular salt, C(6)H(16)NO(+)·Cl(−), two of the C—C—N—O groups in the cation adopt a gauche conformation [torsion angles = 62.86 (11) and −54.95 (13)°] and one an anti conformation [−177.82 (10)°. The cation and anion are linked by an O—H⋯Cl hydrogen bond. The extended structure displays C—H⋯Cl and C—H⋯O hydrogen bonds, resulting in layers lying parallel to the (100) plane: further C—H⋯Cl contacts connect the sheets into a three-dimensional network. International Union of Crystallography 2016-10-21 /pmc/articles/PMC5095844/ /pubmed/27840719 http://dx.doi.org/10.1107/S2056989016016169 Text en © Averkiev et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Averkiev, Boris B.
Valencia, Bianca C.
Getmanenko, Yulia A.
Timofeeva, Tatiana V.
Crystal structure of N,N,N-tri­ethyl­hydroxyl­ammonium chloride
title Crystal structure of N,N,N-tri­ethyl­hydroxyl­ammonium chloride
title_full Crystal structure of N,N,N-tri­ethyl­hydroxyl­ammonium chloride
title_fullStr Crystal structure of N,N,N-tri­ethyl­hydroxyl­ammonium chloride
title_full_unstemmed Crystal structure of N,N,N-tri­ethyl­hydroxyl­ammonium chloride
title_short Crystal structure of N,N,N-tri­ethyl­hydroxyl­ammonium chloride
title_sort crystal structure of n,n,n-tri­ethyl­hydroxyl­ammonium chloride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095844/
https://www.ncbi.nlm.nih.gov/pubmed/27840719
http://dx.doi.org/10.1107/S2056989016016169
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