Crystal structure of 9-(di­bromo­meth­yl)-1,1-di­fluoro-3,7-dimethyl-1H-[1,3,5,2]oxadi­aza­borinino[3,4-a][1,8]naphthyridin-11-ium-1-uide

The mol­ecule of the title 1,8-naphthyridine-BF(2) derivative, C(12)H(10)BBr(2)F(2)N(3)O, is located on a mirror plane running parallel to the entire ring system and the attached methyl C atoms. Individual mol­ecules are stacked along the b-axis direction. The cohesion in the crystal structure is ac...

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Detalles Bibliográficos
Autores principales: Wang, Bang Zhong, Zhou, Jun Ping, Zhou, Yong, Luo, Jian Song, Chi, Shao Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095851/
https://www.ncbi.nlm.nih.gov/pubmed/27840726
http://dx.doi.org/10.1107/S2056989016016704
Descripción
Sumario:The mol­ecule of the title 1,8-naphthyridine-BF(2) derivative, C(12)H(10)BBr(2)F(2)N(3)O, is located on a mirror plane running parallel to the entire ring system and the attached methyl C atoms. Individual mol­ecules are stacked along the b-axis direction. The cohesion in the crystal structure is accomplished by C—H⋯F hydrogen bonds and additional off-set π–π inter­actions [centroid-to-centroid distance = 3.6392 (9) Å, slippage 0.472 Å], leading to the formation of a three-dimensional supra­molecular network.

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