Channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)N(2)H(8)·5H(2)O}(n)

The coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·5H(2)O}(n), systematic name: poly[[bis­(μ(2)-4,4′-bi­pyridine)(μ(2)-hexa­fluorido­silicato)copper(II)] 4,4′-bi­pyridine disolvate penta­hydrate], contains pores which are filled with water and 4,4′-bi­pyridine mol­ecules. As a r...

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Autores principales: Aubert, Emmanuel, Doudouh, Abdelatif, Peluso, Paola, Mamane, Victor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095855/
https://www.ncbi.nlm.nih.gov/pubmed/27840730
http://dx.doi.org/10.1107/S2056989016016686
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author Aubert, Emmanuel
Doudouh, Abdelatif
Peluso, Paola
Mamane, Victor
author_facet Aubert, Emmanuel
Doudouh, Abdelatif
Peluso, Paola
Mamane, Victor
author_sort Aubert, Emmanuel
collection PubMed
description The coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·5H(2)O}(n), systematic name: poly[[bis­(μ(2)-4,4′-bi­pyridine)(μ(2)-hexa­fluorido­silicato)copper(II)] 4,4′-bi­pyridine disolvate penta­hydrate], contains pores which are filled with water and 4,4′-bi­pyridine mol­ecules. As a result of the presence of these ordered species, the framework changes its symmetry from P4/mmm to P2(1)/c. The 4,4′-bi­pyridine guest mol­ecules form chains inside the 6.5 × 6.9 Å pores parallel to [100] in which the mol­ecules inter­act through π–π stacking. Ordered water mol­ecules form infinite hydrogen-bonded chains inside a second pore system (1.6 × 5.3 Å free aperture) perpendicular to the 4,4′-bi­pyridine channels.
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spelling pubmed-50958552016-11-11 Channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)N(2)H(8)·5H(2)O}(n) Aubert, Emmanuel Doudouh, Abdelatif Peluso, Paola Mamane, Victor Acta Crystallogr E Crystallogr Commun Research Communications The coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)H(8)N(2)·5H(2)O}(n), systematic name: poly[[bis­(μ(2)-4,4′-bi­pyridine)(μ(2)-hexa­fluorido­silicato)copper(II)] 4,4′-bi­pyridine disolvate penta­hydrate], contains pores which are filled with water and 4,4′-bi­pyridine mol­ecules. As a result of the presence of these ordered species, the framework changes its symmetry from P4/mmm to P2(1)/c. The 4,4′-bi­pyridine guest mol­ecules form chains inside the 6.5 × 6.9 Å pores parallel to [100] in which the mol­ecules inter­act through π–π stacking. Ordered water mol­ecules form infinite hydrogen-bonded chains inside a second pore system (1.6 × 5.3 Å free aperture) perpendicular to the 4,4′-bi­pyridine channels. International Union of Crystallography 2016-10-25 /pmc/articles/PMC5095855/ /pubmed/27840730 http://dx.doi.org/10.1107/S2056989016016686 Text en © Aubert et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Aubert, Emmanuel
Doudouh, Abdelatif
Peluso, Paola
Mamane, Victor
Channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)N(2)H(8)·5H(2)O}(n)
title Channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)N(2)H(8)·5H(2)O}(n)
title_full Channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)N(2)H(8)·5H(2)O}(n)
title_fullStr Channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)N(2)H(8)·5H(2)O}(n)
title_full_unstemmed Channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)N(2)H(8)·5H(2)O}(n)
title_short Channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[Cu(SiF(6))(C(10)H(8)N(2))(2)]·2C(10)N(2)H(8)·5H(2)O}(n)
title_sort channels with ordered water and bipyridine mol­ecules in the porous coordination polymer {[cu(sif(6))(c(10)h(8)n(2))(2)]·2c(10)n(2)h(8)·5h(2)o}(n)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095855/
https://www.ncbi.nlm.nih.gov/pubmed/27840730
http://dx.doi.org/10.1107/S2056989016016686
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