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Crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) O (1):O (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) N (1):N (4′)]dizinc]

In the title polymeric Zn(II) complex, [Zn(2)(C(10)H(4)O(8))Cl(2)(C(20)H(14)N(4))(2)](n), the Zn(II) cations are bridged by both 2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ate dianions and 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligands, forming ladder-like polymeric chains propagating along [1-10]....

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Detalles Bibliográficos
Autores principales: Tian, Yue, Xu, Sha-Sha, Su, Jian, Zhang, Yang, Zhao, Shao-Shuai, Tian, Yu-Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095857/
https://www.ncbi.nlm.nih.gov/pubmed/27840732
http://dx.doi.org/10.1107/S2056989016016285
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author Tian, Yue
Xu, Sha-Sha
Su, Jian
Zhang, Yang
Zhao, Shao-Shuai
Tian, Yu-Peng
author_facet Tian, Yue
Xu, Sha-Sha
Su, Jian
Zhang, Yang
Zhao, Shao-Shuai
Tian, Yu-Peng
author_sort Tian, Yue
collection PubMed
description In the title polymeric Zn(II) complex, [Zn(2)(C(10)H(4)O(8))Cl(2)(C(20)H(14)N(4))(2)](n), the Zn(II) cations are bridged by both 2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ate dianions and 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligands, forming ladder-like polymeric chains propagating along [1-10]. The Cl(−) anion further coordinates the Zn(II) cation to complete a distorted tetra­hedral environment. In the 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligand, the three sideward pyridine rings are twisted with respect to the central pyridine ring by 39.27 (12), 14.89 (13) and 3.36 (13)°, respectively. In the crystal, classical O—H⋯N hydrogen bonds and weak C—H⋯O and C—H⋯Cl hydrogen bonds link the chains into a three-dimensional supra­molecular architecture. π–π stacking is observed between the pyridine and benzene rings of neighbouring polymeric chains, with a centroid-to-centroid distance of 3.7280 (14) Å.
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spelling pubmed-50958572016-11-11 Crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) O (1):O (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) N (1):N (4′)]dizinc] Tian, Yue Xu, Sha-Sha Su, Jian Zhang, Yang Zhao, Shao-Shuai Tian, Yu-Peng Acta Crystallogr E Crystallogr Commun Research Communications In the title polymeric Zn(II) complex, [Zn(2)(C(10)H(4)O(8))Cl(2)(C(20)H(14)N(4))(2)](n), the Zn(II) cations are bridged by both 2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ate dianions and 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligands, forming ladder-like polymeric chains propagating along [1-10]. The Cl(−) anion further coordinates the Zn(II) cation to complete a distorted tetra­hedral environment. In the 4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine ligand, the three sideward pyridine rings are twisted with respect to the central pyridine ring by 39.27 (12), 14.89 (13) and 3.36 (13)°, respectively. In the crystal, classical O—H⋯N hydrogen bonds and weak C—H⋯O and C—H⋯Cl hydrogen bonds link the chains into a three-dimensional supra­molecular architecture. π–π stacking is observed between the pyridine and benzene rings of neighbouring polymeric chains, with a centroid-to-centroid distance of 3.7280 (14) Å. International Union of Crystallography 2016-10-28 /pmc/articles/PMC5095857/ /pubmed/27840732 http://dx.doi.org/10.1107/S2056989016016285 Text en © Tian et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Tian, Yue
Xu, Sha-Sha
Su, Jian
Zhang, Yang
Zhao, Shao-Shuai
Tian, Yu-Peng
Crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) O (1):O (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) N (1):N (4′)]dizinc]
title Crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) O (1):O (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) N (1):N (4′)]dizinc]
title_full Crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) O (1):O (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) N (1):N (4′)]dizinc]
title_fullStr Crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) O (1):O (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) N (1):N (4′)]dizinc]
title_full_unstemmed Crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) O (1):O (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) N (1):N (4′)]dizinc]
title_short Crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) O (1):O (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) N (1):N (4′)]dizinc]
title_sort crystal structure of poly[di­chlorido­(μ-2,5-di­carb­oxy­benzene-1,4-di­carboxyl­ato-κ(2) o (1):o (4))bis­[μ-4′-(pyridin-3-yl)-4,2′:6′,4′′-terpyridine-κ(2) n (1):n (4′)]dizinc]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095857/
https://www.ncbi.nlm.nih.gov/pubmed/27840732
http://dx.doi.org/10.1107/S2056989016016285
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