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Crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst
The title compound, C(14)H(18)N(4)O, synthesized from an unconventional microwave-assisted method using caesium carbonate as catalyst, has an approximately planar conformation with the pyridyl and pyrazole rings inclined by a dihedral angle of 7.94 (3)°, allowing the formation of an intramolecular...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095859/ https://www.ncbi.nlm.nih.gov/pubmed/27840734 http://dx.doi.org/10.1107/S2056989016017187 |
| _version_ | 1782465363391283200 |
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| author | Macías, Mario A. Orrego-Hernández, Jessica Portilla, Jaime |
| author_facet | Macías, Mario A. Orrego-Hernández, Jessica Portilla, Jaime |
| author_sort | Macías, Mario A. |
| collection | PubMed |
| description | The title compound, C(14)H(18)N(4)O, synthesized from an unconventional microwave-assisted method using caesium carbonate as catalyst, has an approximately planar conformation with the pyridyl and pyrazole rings inclined by a dihedral angle of 7.94 (3)°, allowing the formation of an intramolecular N—H⋯N hydrogen bond. The supramolecular assembly has a three-dimensional arrangement controlled mainly by weak C—H⋯O and C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-5095859 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2016 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-50958592016-11-11 Crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst Macías, Mario A. Orrego-Hernández, Jessica Portilla, Jaime Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(14)H(18)N(4)O, synthesized from an unconventional microwave-assisted method using caesium carbonate as catalyst, has an approximately planar conformation with the pyridyl and pyrazole rings inclined by a dihedral angle of 7.94 (3)°, allowing the formation of an intramolecular N—H⋯N hydrogen bond. The supramolecular assembly has a three-dimensional arrangement controlled mainly by weak C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2016-10-28 /pmc/articles/PMC5095859/ /pubmed/27840734 http://dx.doi.org/10.1107/S2056989016017187 Text en © Macías et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Macías, Mario A. Orrego-Hernández, Jessica Portilla, Jaime Crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst |
| title | Crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst |
| title_full | Crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst |
| title_fullStr | Crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst |
| title_full_unstemmed | Crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst |
| title_short | Crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1H-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst |
| title_sort | crystal structure of 5-butylamino-3-methyl-1-(pyridin-2-yl)-1h-pyrazole-4-carbaldehyde obtained from a microwave-assisted reaction using caesium carbonate as catalyst |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5095859/ https://www.ncbi.nlm.nih.gov/pubmed/27840734 http://dx.doi.org/10.1107/S2056989016017187 |
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