Negative thermal expansion induced by intermetallic charge transfer

Suppression of thermal expansion is of great importance for industry. Negative thermal expansion (NTE) materials which shrink on heating and expand on cooling are therefore attracting keen attention. Here we provide a brief overview of NTE induced by intermetallic charge transfer in A-site ordered d...

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Detalles Bibliográficos
Autores principales: Azuma, Masaki, Oka, Kengo, Nabetani, Koichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2015
Materias:
Reviews
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5099838/
https://www.ncbi.nlm.nih.gov/pubmed/27877801
http://dx.doi.org/10.1088/1468-6996/16/3/034904
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author Azuma, Masaki
Oka, Kengo
Nabetani, Koichiro
author_facet Azuma, Masaki
Oka, Kengo
Nabetani, Koichiro
author_sort Azuma, Masaki
collection PubMed
description Suppression of thermal expansion is of great importance for industry. Negative thermal expansion (NTE) materials which shrink on heating and expand on cooling are therefore attracting keen attention. Here we provide a brief overview of NTE induced by intermetallic charge transfer in A-site ordered double perovskites SaCu(3)Fe(4)O(12) and LaCu(3)Fe(4−x)Mn(x)O(12), as well as in Bi or Ni substituted BiNiO(3). The last compound shows a colossal dilatometric linear thermal expansion coefficient exceeding −70 × 10(−6) K(−1) near room temperature, in the temperature range which can be controlled by substitution.
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spelling pubmed-50998382016-11-22 Negative thermal expansion induced by intermetallic charge transfer Azuma, Masaki Oka, Kengo Nabetani, Koichiro Sci Technol Adv Mater Reviews Suppression of thermal expansion is of great importance for industry. Negative thermal expansion (NTE) materials which shrink on heating and expand on cooling are therefore attracting keen attention. Here we provide a brief overview of NTE induced by intermetallic charge transfer in A-site ordered double perovskites SaCu(3)Fe(4)O(12) and LaCu(3)Fe(4−x)Mn(x)O(12), as well as in Bi or Ni substituted BiNiO(3). The last compound shows a colossal dilatometric linear thermal expansion coefficient exceeding −70 × 10(−6) K(−1) near room temperature, in the temperature range which can be controlled by substitution. Taylor & Francis 2015-06-02 /pmc/articles/PMC5099838/ /pubmed/27877801 http://dx.doi.org/10.1088/1468-6996/16/3/034904 Text en © 2015 National Institute for Materials Science http://creativecommons.org/licenses/by/3.0/ Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence (http://creativecommons.org/licenses/by/3.0) . Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
spellingShingle Reviews
Azuma, Masaki
Oka, Kengo
Nabetani, Koichiro
Negative thermal expansion induced by intermetallic charge transfer
title Negative thermal expansion induced by intermetallic charge transfer
title_full Negative thermal expansion induced by intermetallic charge transfer
title_fullStr Negative thermal expansion induced by intermetallic charge transfer
title_full_unstemmed Negative thermal expansion induced by intermetallic charge transfer
title_short Negative thermal expansion induced by intermetallic charge transfer
title_sort negative thermal expansion induced by intermetallic charge transfer
topic Reviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5099838/
https://www.ncbi.nlm.nih.gov/pubmed/27877801
http://dx.doi.org/10.1088/1468-6996/16/3/034904
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AT okakengo negativethermalexpansioninducedbyintermetallicchargetransfer
AT nabetanikoichiro negativethermalexpansioninducedbyintermetallicchargetransfer

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