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Varied roles of Pb in transition-metal PbMO(3) perovskites (M = Ti, V, Cr, Mn, Fe, Ni, Ru)
Different structural chemistries resulting from the Pb(2+) lone-pair electrons in the PbMO(3) perovskites are reviewed. The Pb(2+) lone-pair electrons enhance the ferroelectric transition temperature in PbTiO(3), stabilize vanadyl formation in PbVO(3), and induce a disproportionation reaction of Cr(...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Taylor & Francis
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5099851/ https://www.ncbi.nlm.nih.gov/pubmed/27877814 http://dx.doi.org/10.1088/1468-6996/16/3/036003 |