Total Synthesis, Structure, and Biological Activity of Adenosylrhodibalamin, the Non‐Natural Rhodium Homologue of Coenzyme B(12)

B(12) is unique among the vitamins as it is biosynthesized only by certain prokaryotes. The complexity of its synthesis relates to its distinctive cobalt corrin structure, which is essential for B(12) biochemistry and renders coenzyme B(12) (AdoCbl) so intriguingly suitable for enzymatic radical rea...

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Detalles Bibliográficos
Autores principales: Widner, Florian J., Lawrence, Andrew D., Deery, Evelyne, Heldt, Dana, Frank, Stefanie, Gruber, Karl, Wurst, Klaus, Warren, Martin J., Kräutler, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5103170/
https://www.ncbi.nlm.nih.gov/pubmed/27355790
http://dx.doi.org/10.1002/anie.201603738

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