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Transforming LiTMP Lithiation of Challenging Diazines through Gallium Alkyl Trans‐Metal‐Trapping

This study establishes a new trans‐metal‐trapping (TMT) procedure based on a mixture of LiTMP (the base) and tris(trimethylsilylmethyl)gallium [Ga(CH(2)SiMe(3))(3), GaR(3)] (the trap) that, operating in a tandem manner, is effective for the regioselective deprotonation of sensitive diazines in hydro...

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Detalles Bibliográficos
Autores principales:	Uzelac, Marina, Kennedy, Alan R., Hevia, Eva, Mulvey, Robert E.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113679/ https://www.ncbi.nlm.nih.gov/pubmed/27647741 http://dx.doi.org/10.1002/anie.201607284

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