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Torsional and Electronic Factors Control the C−H⋅⋅⋅O Interaction

The precise role of non‐conventional hydrogen bonds such as the C−H⋅⋅⋅O interaction in influencing the conformation of small molecules remains unresolved. Here we survey a series of β‐turn mimetics using X‐ray crystallography and NMR spectroscopy in conjunction with quantum calculation, and conclude...

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Detalles Bibliográficos
Autores principales:	Driver, Russell W., Claridge, Timothy D. W., Scheiner, Steve, Smith, Martin D.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2016
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113693/ https://www.ncbi.nlm.nih.gov/pubmed/27709689 http://dx.doi.org/10.1002/chem.201602905

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