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Ground‐State Chemical Reactivity under Vibrational Coupling to the Vacuum Electromagnetic Field
The ground‐state deprotection of a simple alkynylsilane is studied under vibrational strong coupling to the zero‐point fluctuations, or vacuum electromagnetic field, of a resonant IR microfluidic cavity. The reaction rate decreased by a factor of up to 5.5 when the Si−C vibrational stretching modes...
Autores principales: | Thomas, Anoop, George, Jino, Shalabney, Atef, Dryzhakov, Marian, Varma, Sreejith J., Moran, Joseph, Chervy, Thibault, Zhong, Xiaolan, Devaux, Eloïse, Genet, Cyriaque, Hutchison, James A., Ebbesen, Thomas W. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113700/ https://www.ncbi.nlm.nih.gov/pubmed/27529831 http://dx.doi.org/10.1002/anie.201605504 |
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