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Overcoming the Crystallization Bottleneck: A Family of Gigantic Inorganic {Pd(x)}(L) (x=84, 72) Palladium Macrocycles Discovered using Solution Techniques
The {Pd(84)}(Ac) wheel, initially discovered serendipitously, is the only reported giant palladium macrocycle—a unique structure that spontaneously assembles from small building blocks. Analogues of this structure are elusive. A new modular route to {Pd(84)}(Ac) is described, allowing incorporation...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113701/ https://www.ncbi.nlm.nih.gov/pubmed/27634480 http://dx.doi.org/10.1002/anie.201606005 |