Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers

The formation of unusual multilayered parallel lamellae‐in‐lamellae in symmetric supramolecular double‐comb diblock copolymers is presented. While keeping the concentration of surfactant fixed, the number of internal layers was found to increase with molecular weight M up to 34 for the largest block...

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Detalles Bibliográficos
Autores principales: Hofman, Anton H., Reza, Mehedi, Ruokolainen, Janne, ten Brinke, Gerrit, Loos, Katja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113798/
https://www.ncbi.nlm.nih.gov/pubmed/27633842
http://dx.doi.org/10.1002/anie.201606890
Descripción
Sumario:The formation of unusual multilayered parallel lamellae‐in‐lamellae in symmetric supramolecular double‐comb diblock copolymers is presented. While keeping the concentration of surfactant fixed, the number of internal layers was found to increase with molecular weight M up to 34 for the largest block copolymer. The number of internal structures n was established to scale as M (0.67) and therefore enables easy design of such structures with great precision.

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