Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers

The formation of unusual multilayered parallel lamellae‐in‐lamellae in symmetric supramolecular double‐comb diblock copolymers is presented. While keeping the concentration of surfactant fixed, the number of internal layers was found to increase with molecular weight M up to 34 for the largest block...

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Autores principales: Hofman, Anton H., Reza, Mehedi, Ruokolainen, Janne, ten Brinke, Gerrit, Loos, Katja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113798/
https://www.ncbi.nlm.nih.gov/pubmed/27633842
http://dx.doi.org/10.1002/anie.201606890
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author Hofman, Anton H.
Reza, Mehedi
Ruokolainen, Janne
ten Brinke, Gerrit
Loos, Katja
author_facet Hofman, Anton H.
Reza, Mehedi
Ruokolainen, Janne
ten Brinke, Gerrit
Loos, Katja
author_sort Hofman, Anton H.
collection PubMed
description The formation of unusual multilayered parallel lamellae‐in‐lamellae in symmetric supramolecular double‐comb diblock copolymers is presented. While keeping the concentration of surfactant fixed, the number of internal layers was found to increase with molecular weight M up to 34 for the largest block copolymer. The number of internal structures n was established to scale as M (0.67) and therefore enables easy design of such structures with great precision.
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spelling pubmed-51137982016-12-02 Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers Hofman, Anton H. Reza, Mehedi Ruokolainen, Janne ten Brinke, Gerrit Loos, Katja Angew Chem Int Ed Engl Communications The formation of unusual multilayered parallel lamellae‐in‐lamellae in symmetric supramolecular double‐comb diblock copolymers is presented. While keeping the concentration of surfactant fixed, the number of internal layers was found to increase with molecular weight M up to 34 for the largest block copolymer. The number of internal structures n was established to scale as M (0.67) and therefore enables easy design of such structures with great precision. John Wiley and Sons Inc. 2016-10-06 2016-10-10 /pmc/articles/PMC5113798/ /pubmed/27633842 http://dx.doi.org/10.1002/anie.201606890 Text en © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs (http://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Hofman, Anton H.
Reza, Mehedi
Ruokolainen, Janne
ten Brinke, Gerrit
Loos, Katja
Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers
title Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers
title_full Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers
title_fullStr Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers
title_full_unstemmed Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers
title_short Hierarchical Layer Engineering Using Supramolecular Double‐Comb Diblock Copolymers
title_sort hierarchical layer engineering using supramolecular double‐comb diblock copolymers
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5113798/
https://www.ncbi.nlm.nih.gov/pubmed/27633842
http://dx.doi.org/10.1002/anie.201606890
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AT ruokolainenjanne hierarchicallayerengineeringusingsupramoleculardoublecombdiblockcopolymers
AT tenbrinkegerrit hierarchicallayerengineeringusingsupramoleculardoublecombdiblockcopolymers
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