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MIDA boronates are hydrolysed fast and slow by two different mechanisms

MIDA boronates (N-methylimidodiacetic boronic acid esters) serve as an increasingly general platform for building-block-based small molecule construction, largely due to the dramatic and general rate differences with which they are hydrolysed under various basic conditions. Yet the mechanistic under...

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Detalles Bibliográficos
Autores principales:	Gonzalez, Jorge A., Ogba, O. Maduka, Morehouse, Gregory F., Rosson, Nicholas, Houk, Kendall N., Leach, Andrew G., Cheong, Paul H.-Y., Burke, Martin D., Lloyd-Jones, Guy C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	2016
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5115273/ https://www.ncbi.nlm.nih.gov/pubmed/27768100 http://dx.doi.org/10.1038/nchem.2571

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