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Switching Dielectric Constant Near Room Temperature in a Molecular Crystal

The organic salt bis(2‐chloroethyl)amine hydrochloride shows a sharp switching of its dielectric constant at 320 K. The switching property originates from the dynamic changes of the (2‐chloroethyl)ammonium cation between frozen and motional states, corresponding to a structural phase transition. [Im...

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Detalles Bibliográficos
Autores principales: Shao, Xiu‐Dan, Zhang, Xi, Shi, Chao, Yao, Ye‐Feng, Zhang, Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5115362/
https://www.ncbi.nlm.nih.gov/pubmed/27980939
http://dx.doi.org/10.1002/advs.201500029
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author Shao, Xiu‐Dan
Zhang, Xi
Shi, Chao
Yao, Ye‐Feng
Zhang, Wen
author_facet Shao, Xiu‐Dan
Zhang, Xi
Shi, Chao
Yao, Ye‐Feng
Zhang, Wen
author_sort Shao, Xiu‐Dan
collection PubMed
description The organic salt bis(2‐chloroethyl)amine hydrochloride shows a sharp switching of its dielectric constant at 320 K. The switching property originates from the dynamic changes of the (2‐chloroethyl)ammonium cation between frozen and motional states, corresponding to a structural phase transition. [Image: see text]
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spelling pubmed-51153622016-12-15 Switching Dielectric Constant Near Room Temperature in a Molecular Crystal Shao, Xiu‐Dan Zhang, Xi Shi, Chao Yao, Ye‐Feng Zhang, Wen Adv Sci (Weinh) Communications The organic salt bis(2‐chloroethyl)amine hydrochloride shows a sharp switching of its dielectric constant at 320 K. The switching property originates from the dynamic changes of the (2‐chloroethyl)ammonium cation between frozen and motional states, corresponding to a structural phase transition. [Image: see text] John Wiley and Sons Inc. 2015-04-14 /pmc/articles/PMC5115362/ /pubmed/27980939 http://dx.doi.org/10.1002/advs.201500029 Text en © 2015 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Shao, Xiu‐Dan
Zhang, Xi
Shi, Chao
Yao, Ye‐Feng
Zhang, Wen
Switching Dielectric Constant Near Room Temperature in a Molecular Crystal
title Switching Dielectric Constant Near Room Temperature in a Molecular Crystal
title_full Switching Dielectric Constant Near Room Temperature in a Molecular Crystal
title_fullStr Switching Dielectric Constant Near Room Temperature in a Molecular Crystal
title_full_unstemmed Switching Dielectric Constant Near Room Temperature in a Molecular Crystal
title_short Switching Dielectric Constant Near Room Temperature in a Molecular Crystal
title_sort switching dielectric constant near room temperature in a molecular crystal
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5115362/
https://www.ncbi.nlm.nih.gov/pubmed/27980939
http://dx.doi.org/10.1002/advs.201500029
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