Multistimuli Sensitive Behavior of Novel Bodipy‐Involved Pillar[5]arene‐Based Fluorescent [2]Rotaxane and Its Supramolecular Gel

Fluorescent [2]rotaxane BC12P5 is successfully constructed with 1,4‐diethoxypillar[5]arene as wheel over a long alkyl axle with Bodipy chromophore as one stopper for the first time. NMR spectra clearly reveal its molecular shuttle nature triggered by multiple external stimuli including solvent polarity and temperature. In particular, the fluorescence nature introduced into [2]rotaxane BC12P5 renders it a good sensor for the external stimuli. Nevertheless, the supramolecular gel successfully fabricated from this novel rotaxane system via self‐assembly in dimethyl sulfoxide (DMSO) also shows reversible gel–sol phase transition upon multiple external stimuli such as heating/cooling, shaking/resting, or the addition of different anions. Interestingly, exposure of the supramolecular gel film to HCl or ammonia vapor induces the change in the film fluorescence intensity, endowing this system with a potential application in gas detecting.