Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd(4) Hybridization

A quasi‐sd(4) hybridization state for group VIIIB and IB face‐centered cubic (FCC) transition metals in low‐dimensional nanostructures is identified, in contrast to the sd(5) hybridization state in bulk. For Au, a novel three‐shelled nanowire is designed with a hexagonal close‐packed core in the sd(...

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Autores principales: Yang, Jianhui, Zhang, Qiuju, Chen, Liang, Wang, Gang, Chen, Xiaolong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5115452/
https://www.ncbi.nlm.nih.gov/pubmed/27981017
http://dx.doi.org/10.1002/advs.201500314
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author Yang, Jianhui
Zhang, Qiuju
Chen, Liang
Wang, Gang
Chen, Xiaolong
author_facet Yang, Jianhui
Zhang, Qiuju
Chen, Liang
Wang, Gang
Chen, Xiaolong
author_sort Yang, Jianhui
collection PubMed
description A quasi‐sd(4) hybridization state for group VIIIB and IB face‐centered cubic (FCC) transition metals in low‐dimensional nanostructures is identified, in contrast to the sd(5) hybridization state in bulk. For Au, a novel three‐shelled nanowire is designed with a hexagonal close‐packed core in the sd(5) hybridization, wrapped by FCC‐(111) shell that adopts the quasi‐sd(4) hybridization. This new nanostructure exhibits remarkable stability and electronic properties. [Image: see text]
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spelling pubmed-51154522016-12-15 Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd(4) Hybridization Yang, Jianhui Zhang, Qiuju Chen, Liang Wang, Gang Chen, Xiaolong Adv Sci (Weinh) Communications A quasi‐sd(4) hybridization state for group VIIIB and IB face‐centered cubic (FCC) transition metals in low‐dimensional nanostructures is identified, in contrast to the sd(5) hybridization state in bulk. For Au, a novel three‐shelled nanowire is designed with a hexagonal close‐packed core in the sd(5) hybridization, wrapped by FCC‐(111) shell that adopts the quasi‐sd(4) hybridization. This new nanostructure exhibits remarkable stability and electronic properties. [Image: see text] John Wiley and Sons Inc. 2016-01-21 /pmc/articles/PMC5115452/ /pubmed/27981017 http://dx.doi.org/10.1002/advs.201500314 Text en © 2016 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Yang, Jianhui
Zhang, Qiuju
Chen, Liang
Wang, Gang
Chen, Xiaolong
Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd(4) Hybridization
title Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd(4) Hybridization
title_full Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd(4) Hybridization
title_fullStr Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd(4) Hybridization
title_full_unstemmed Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd(4) Hybridization
title_short Formation and Stability of Low‐Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd(4) Hybridization
title_sort formation and stability of low‐dimensional structures for group viiib and ib transition metals: the role of sd(4) hybridization
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5115452/
https://www.ncbi.nlm.nih.gov/pubmed/27981017
http://dx.doi.org/10.1002/advs.201500314
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AT chenliang formationandstabilityoflowdimensionalstructuresforgroupviiibandibtransitionmetalstheroleofsd4hybridization
AT wanggang formationandstabilityoflowdimensionalstructuresforgroupviiibandibtransitionmetalstheroleofsd4hybridization
AT chenxiaolong formationandstabilityoflowdimensionalstructuresforgroupviiibandibtransitionmetalstheroleofsd4hybridization

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