Vacancy‐Contained Tetragonal Na(3)SbS(4) Superionic Conductor

Tetragonal Na(3)SbS(4) is synthesized as a new sodium superionic conductor. The discovery of Na vacancies experimentally verifies previous theoretical predictions. Na vacancies, distorted cubic sulphur sublattices and large Na atomic displacement parameters lead to the ionic conductivity as high as...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhang, Long, Zhang, Dechao, Yang, Kun, Yan, Xinlin, Wang, Limin, Mi, Jianli, Xu, Bo, Li, Yueming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5115597/
https://www.ncbi.nlm.nih.gov/pubmed/27980981
http://dx.doi.org/10.1002/advs.201600089
_version_ 1782468535178493952
author Zhang, Long
Zhang, Dechao
Yang, Kun
Yan, Xinlin
Wang, Limin
Mi, Jianli
Xu, Bo
Li, Yueming
author_facet Zhang, Long
Zhang, Dechao
Yang, Kun
Yan, Xinlin
Wang, Limin
Mi, Jianli
Xu, Bo
Li, Yueming
author_sort Zhang, Long
collection PubMed
description Tetragonal Na(3)SbS(4) is synthesized as a new sodium superionic conductor. The discovery of Na vacancies experimentally verifies previous theoretical predictions. Na vacancies, distorted cubic sulphur sublattices and large Na atomic displacement parameters lead to the ionic conductivity as high as 3 mS cm(−1), a value significantly higher than those of state‐of‐the‐art sodium sulfide electrolytes. [Image: see text]
format Online
Article
Text
id pubmed-5115597
institution National Center for Biotechnology Information
language English
publishDate 2016
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-51155972016-12-15 Vacancy‐Contained Tetragonal Na(3)SbS(4) Superionic Conductor Zhang, Long Zhang, Dechao Yang, Kun Yan, Xinlin Wang, Limin Mi, Jianli Xu, Bo Li, Yueming Adv Sci (Weinh) Communications Tetragonal Na(3)SbS(4) is synthesized as a new sodium superionic conductor. The discovery of Na vacancies experimentally verifies previous theoretical predictions. Na vacancies, distorted cubic sulphur sublattices and large Na atomic displacement parameters lead to the ionic conductivity as high as 3 mS cm(−1), a value significantly higher than those of state‐of‐the‐art sodium sulfide electrolytes. [Image: see text] John Wiley and Sons Inc. 2016-04-23 /pmc/articles/PMC5115597/ /pubmed/27980981 http://dx.doi.org/10.1002/advs.201600089 Text en © 2016 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim This is an open access article under the terms of the Creative Commons Attribution (http://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Zhang, Long
Zhang, Dechao
Yang, Kun
Yan, Xinlin
Wang, Limin
Mi, Jianli
Xu, Bo
Li, Yueming
Vacancy‐Contained Tetragonal Na(3)SbS(4) Superionic Conductor
title Vacancy‐Contained Tetragonal Na(3)SbS(4) Superionic Conductor
title_full Vacancy‐Contained Tetragonal Na(3)SbS(4) Superionic Conductor
title_fullStr Vacancy‐Contained Tetragonal Na(3)SbS(4) Superionic Conductor
title_full_unstemmed Vacancy‐Contained Tetragonal Na(3)SbS(4) Superionic Conductor
title_short Vacancy‐Contained Tetragonal Na(3)SbS(4) Superionic Conductor
title_sort vacancy‐contained tetragonal na(3)sbs(4) superionic conductor
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5115597/
https://www.ncbi.nlm.nih.gov/pubmed/27980981
http://dx.doi.org/10.1002/advs.201600089
work_keys_str_mv AT zhanglong vacancycontainedtetragonalna3sbs4superionicconductor
AT zhangdechao vacancycontainedtetragonalna3sbs4superionicconductor
AT yangkun vacancycontainedtetragonalna3sbs4superionicconductor
AT yanxinlin vacancycontainedtetragonalna3sbs4superionicconductor
AT wanglimin vacancycontainedtetragonalna3sbs4superionicconductor
AT mijianli vacancycontainedtetragonalna3sbs4superionicconductor
AT xubo vacancycontainedtetragonalna3sbs4superionicconductor
AT liyueming vacancycontainedtetragonalna3sbs4superionicconductor

Ejemplares similares