In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts

The in-situ nano-crystal-to-crystal transformation (SCCT) synthesis provides a powerful approach for tailoring controllable feature shapes and sizes of nano crystals. In this work, three nitrogen-rich energetic nano-crystals based on 5,5′-azotetrazolate(AZT(2−)) Cr(III) salts were synthesized by mea...

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Detalles Bibliográficos
Autores principales: Miao, Yu, Qiu, Yanxuan, Cai, Jiawei, Wang, Zizhou, Yu, Xinwei, Dong, Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5116643/
https://www.ncbi.nlm.nih.gov/pubmed/27869221
http://dx.doi.org/10.1038/srep37587
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author Miao, Yu
Qiu, Yanxuan
Cai, Jiawei
Wang, Zizhou
Yu, Xinwei
Dong, Wen
author_facet Miao, Yu
Qiu, Yanxuan
Cai, Jiawei
Wang, Zizhou
Yu, Xinwei
Dong, Wen
author_sort Miao, Yu
collection PubMed
description The in-situ nano-crystal-to-crystal transformation (SCCT) synthesis provides a powerful approach for tailoring controllable feature shapes and sizes of nano crystals. In this work, three nitrogen-rich energetic nano-crystals based on 5,5′-azotetrazolate(AZT(2−)) Cr(III) salts were synthesized by means of SCCT methodology. SEM and TEM analyses show that the energetic nano-crystals feature a composition- and structure-dependent together with size-dependent thermal stability. Moreover, nano-scale decomposition products can be obtained above 500 °C, providing a new method for preparing metallic oxide nano materials.
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spelling pubmed-51166432016-11-28 In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts Miao, Yu Qiu, Yanxuan Cai, Jiawei Wang, Zizhou Yu, Xinwei Dong, Wen Sci Rep Article The in-situ nano-crystal-to-crystal transformation (SCCT) synthesis provides a powerful approach for tailoring controllable feature shapes and sizes of nano crystals. In this work, three nitrogen-rich energetic nano-crystals based on 5,5′-azotetrazolate(AZT(2−)) Cr(III) salts were synthesized by means of SCCT methodology. SEM and TEM analyses show that the energetic nano-crystals feature a composition- and structure-dependent together with size-dependent thermal stability. Moreover, nano-scale decomposition products can be obtained above 500 °C, providing a new method for preparing metallic oxide nano materials. Nature Publishing Group 2016-11-21 /pmc/articles/PMC5116643/ /pubmed/27869221 http://dx.doi.org/10.1038/srep37587 Text en Copyright © 2016, The Author(s) http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Miao, Yu
Qiu, Yanxuan
Cai, Jiawei
Wang, Zizhou
Yu, Xinwei
Dong, Wen
In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts
title In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts
title_full In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts
title_fullStr In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts
title_full_unstemmed In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts
title_short In-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate Cr(III) salts
title_sort in-situ nano-crystal-to-crystal transformation synthesis of energetic materials based on three 5,5′-azotetrazolate cr(iii) salts
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5116643/
https://www.ncbi.nlm.nih.gov/pubmed/27869221
http://dx.doi.org/10.1038/srep37587
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