Crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1H-cyclo­hepta­[b]pyridine-3-carbo­nitrile

In the title compound, C(11)H(13)N(3)O, the seven-membered ring adopts a conformation such that the three atoms not involved in the aromatic plane lie on the same side of that plane. One hydrazinic H atom forms an intra­molecular hydrogen bond to the O atom; the other forms a classical inter­molecul...

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Detalles Bibliográficos
Autores principales: Elgemeie, Galal H., Jones, Peter G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120696/
https://www.ncbi.nlm.nih.gov/pubmed/27920906
http://dx.doi.org/10.1107/S2056989016012196
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author Elgemeie, Galal H.
Jones, Peter G.
author_facet Elgemeie, Galal H.
Jones, Peter G.
author_sort Elgemeie, Galal H.
collection PubMed
description In the title compound, C(11)H(13)N(3)O, the seven-membered ring adopts a conformation such that the three atoms not involved in the aromatic plane lie on the same side of that plane. One hydrazinic H atom forms an intra­molecular hydrogen bond to the O atom; the other forms a classical inter­molecular hydrogen bond N—H⋯O, which combines with a ‘weak’ H(ar)⋯O inter­action to build up double layers of mol­ecules parallel to the bc plane.
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spelling pubmed-51206962016-12-05 Crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1H-cyclo­hepta­[b]pyridine-3-carbo­nitrile Elgemeie, Galal H. Jones, Peter G. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(11)H(13)N(3)O, the seven-membered ring adopts a conformation such that the three atoms not involved in the aromatic plane lie on the same side of that plane. One hydrazinic H atom forms an intra­molecular hydrogen bond to the O atom; the other forms a classical inter­molecular hydrogen bond N—H⋯O, which combines with a ‘weak’ H(ar)⋯O inter­action to build up double layers of mol­ecules parallel to the bc plane. International Union of Crystallography 2016-08-02 /pmc/articles/PMC5120696/ /pubmed/27920906 http://dx.doi.org/10.1107/S2056989016012196 Text en © Elgemeie and Jones 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Elgemeie, Galal H.
Jones, Peter G.
Crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1H-cyclo­hepta­[b]pyridine-3-carbo­nitrile
title Crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1H-cyclo­hepta­[b]pyridine-3-carbo­nitrile
title_full Crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1H-cyclo­hepta­[b]pyridine-3-carbo­nitrile
title_fullStr Crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1H-cyclo­hepta­[b]pyridine-3-carbo­nitrile
title_full_unstemmed Crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1H-cyclo­hepta­[b]pyridine-3-carbo­nitrile
title_short Crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1H-cyclo­hepta­[b]pyridine-3-carbo­nitrile
title_sort crystal structure of 1-amino-2-oxo-2,5,6,7,8,9-hexa­hydro-1h-cyclo­hepta­[b]pyridine-3-carbo­nitrile
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120696/
https://www.ncbi.nlm.nih.gov/pubmed/27920906
http://dx.doi.org/10.1107/S2056989016012196
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