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Crystal structure of methyl (E)-4-[2-(8-hydroxyquinolin-2-yl)vinyl]benzoate
The title compound, C(19)H(15)NO(3), was synthesized by a Perkin reaction of 2-methyl-8-hydroxyquinoline and 4-formyl-2-methylbenzoate in acetic anhydride under a nitrogen atmosphere. The molecule has an E conformation about the C=C bond, and the quinoline ring system and the benzene ring are i...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120699/ https://www.ncbi.nlm.nih.gov/pubmed/27920909 http://dx.doi.org/10.1107/S205698901601210X |
Sumario: | The title compound, C(19)H(15)NO(3), was synthesized by a Perkin reaction of 2-methyl-8-hydroxyquinoline and 4-formyl-2-methylbenzoate in acetic anhydride under a nitrogen atmosphere. The molecule has an E conformation about the C=C bond, and the quinoline ring system and the benzene ring are inclined to one another by 29.22 (7)°. There is an intramolecular O—H⋯N hydrogen bond in the 8-hydroxyquinoline moiety. In the crystal, molecules are linked by pairs of O—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(28) ring motif. The dimers are linked by C—H⋯O hydrogen bonds and C—H⋯π interactions, forming sheets parallel to plane (10-1). |
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