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Crystal structure of methyl (E)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate

The title compound, C(19)H(15)NO(3), was synthesized by a Perkin reaction of 2-methyl-8-hy­droxy­quinoline and 4-formyl-2-methyl­benzoate in acetic anhydride under a nitro­gen atmosphere. The mol­ecule has an E conformation about the C=C bond, and the quinoline ring system and the benzene ring are i...

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Autores principales: Xu, Yu-Xing, Hu, Wei-Ji, Zhao, Guo-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120699/
https://www.ncbi.nlm.nih.gov/pubmed/27920909
http://dx.doi.org/10.1107/S205698901601210X
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author Xu, Yu-Xing
Hu, Wei-Ji
Zhao, Guo-Liang
author_facet Xu, Yu-Xing
Hu, Wei-Ji
Zhao, Guo-Liang
author_sort Xu, Yu-Xing
collection PubMed
description The title compound, C(19)H(15)NO(3), was synthesized by a Perkin reaction of 2-methyl-8-hy­droxy­quinoline and 4-formyl-2-methyl­benzoate in acetic anhydride under a nitro­gen atmosphere. The mol­ecule has an E conformation about the C=C bond, and the quinoline ring system and the benzene ring are inclined to one another by 29.22 (7)°. There is an intra­molecular O—H⋯N hydrogen bond in the 8-hy­droxy­quinoline moiety. In the crystal, mol­ecules are linked by pairs of O—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(28) ring motif. The dimers are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming sheets parallel to plane (10-1).
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spelling pubmed-51206992016-12-05 Crystal structure of methyl (E)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate Xu, Yu-Xing Hu, Wei-Ji Zhao, Guo-Liang Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(19)H(15)NO(3), was synthesized by a Perkin reaction of 2-methyl-8-hy­droxy­quinoline and 4-formyl-2-methyl­benzoate in acetic anhydride under a nitro­gen atmosphere. The mol­ecule has an E conformation about the C=C bond, and the quinoline ring system and the benzene ring are inclined to one another by 29.22 (7)°. There is an intra­molecular O—H⋯N hydrogen bond in the 8-hy­droxy­quinoline moiety. In the crystal, mol­ecules are linked by pairs of O—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(28) ring motif. The dimers are linked by C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming sheets parallel to plane (10-1). International Union of Crystallography 2016-08-05 /pmc/articles/PMC5120699/ /pubmed/27920909 http://dx.doi.org/10.1107/S205698901601210X Text en © Xu et al. 2016 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Xu, Yu-Xing
Hu, Wei-Ji
Zhao, Guo-Liang
Crystal structure of methyl (E)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate
title Crystal structure of methyl (E)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate
title_full Crystal structure of methyl (E)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate
title_fullStr Crystal structure of methyl (E)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate
title_full_unstemmed Crystal structure of methyl (E)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate
title_short Crystal structure of methyl (E)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate
title_sort crystal structure of methyl (e)-4-[2-(8-hy­droxy­quinolin-2-yl)vin­yl]benzoate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5120699/
https://www.ncbi.nlm.nih.gov/pubmed/27920909
http://dx.doi.org/10.1107/S205698901601210X
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